I look forward to the 3.2 release, as I will use most of those improvements.
I'm not sure why, but most of the 3.3 items are not valuable to me, other than the Themes. I'm not sure why virtualization is such a big deal, other than performance of the grid with a lot of rows. This is an uncommon problem for me at the moment.
I could use the Export to PDF, calculated columns, WPF 4.0 alignment, integration into VS 2010, library of Cell Validation rules, more themes, better Master/Detail support in general, and much better spreadsheet-type features
BTW, I'm still trying to figure out how to make data-entry work with using Tab and Enter keys as the only navigation keys - just like Excel. I have been using the grid for 7 months.
Also, the InsertionRow/InsertionCell seems like it is not very mature, and needs some work. We have had to limit our usage of the InsertionRow due to several problems/exceptions that happen in typical usage.